Activation of H2O2 by Chiral Confined Bronsted Acids: A Highly Enantioselective Catalytic Sulfoxidation

被引：187

作者：

Liao, Saihu ^{[1
]}

Coric, Ilija ^{[1
]}

Wang, Qinggang ^{[1
]}

List, Benjamin ^{[1
]}

机构：

[1] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2012年 / 134卷 / 26期

基金：

欧洲研究理事会;

关键词：

ASYMMETRIC OXIDATION; HYDROGEN-PEROXIDE; ALPHA; BETA-UNSATURATED KETONES; CHEMOSELECTIVE OXIDATION; SULFIDE OXIDATION; PHOSPHORIC-ACID; EPOXIDATION; COMPLEX; HYDROPEROXIDES; RESOLUTION;

D O I：

10.1021/ja3035637

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Confined chiral Bronsted acids are shown to catalyze asymmetric oxidations of sulfides to sulfoxides with hydrogen peroxide. The wide generality and high enantioselectivity of the developed method compare even to the best metal-based systems and suggest utility in other asymmetric oxidations.

引用

页码：10765 / 10768

页数：4

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