Synthetic applications of nonmetal catalysts for homogeneous oxidations

被引：441

作者：

Adam, W

Saha-Möller, CR

Ganeshpure, PA ^{[1
]}

机构：

[1] Indian Petrochem Corp Ltd, Res Ctr, Baroda 391346, Gujarat, India

[2] Univ Wurzburg, Inst Organ Chem, D-97074 Wurzburg, Germany

来源：

CHEMICAL REVIEWS | 2001年 / 101卷 / 11期

关键词：

D O I：

10.1021/cr000019k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthetic applications of nonmetal catalysts for homogeneous oxidations were discussed. The perhydrate-mediated, ketone-catalyzed oxidations which included epoxidations, heteroatom oxidations, arene oxidations and miscellaneous catalytic oxidations were examined. The oxaziridine-mediated imine-catalyzed oxidations which included racemic sulfide oxidations and asymmetric sulfide oxidations were also elaborated.

引用

页码：3499 / 3548

页数：50

共 250 条

[1] HYDROXY-DIRECTED REGIOSELECTIVE AND DIASTEREOSELECTIVE ENE REACTION OF SINGLET OXYGEN WITH CHIRAL ALLYLIC ALCOHOLS
ADAM, W
NESTLER, B
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (12) : 5041 - 5049
[2] (Z)-3-METHYL-3-PENTEN-2-OL AS STEREOCHEMICAL PROBE FOR 1,2 VERSUS 1,3 ALLYLIC STRAIN IN THE PHOTOOXYGENATION AND EPOXIDATION OF CHIRAL ALLYLIC ALCOHOLS
ADAM, W
NESTLER, B
[J]. TETRAHEDRON LETTERS, 1993, 34 (04) : 611 - 614
[3] Synthesis of optically active C2-symmetric ketones for the asymmetric epoxidation of prochiral olefins by dioxiranes generated in situ with Caroate™ as a peroxide source
Adam, W
Zhao, CG
[J]. TETRAHEDRON-ASYMMETRY, 1997, 8 (24) : 3995 - 3998
[4] Adam W, 1997, LIEBIGS ANN-RECL, P547
[5] SYNTHESIS OF THE 2,3-EPOXY-2,3-DIHYDRO-2,3-DIMETHYLBENZO[B]FURAN, THE PROPOSED ULTIMATE MUTAGEN OF THE BENZOFURAN DIOXETANES
ADAM, W
HADJIARAPOGLOU, L
MOSANDL, T
SAHAMOLLER, CR
WILD, D
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1991, 30 (02): : 200 - 202
[6] Asymmetric C-H oxidation of vic-diols to α-hydroxy ketones by a fructose-derived dioxirane:: Electronic effects on the enantioselectivity of oxygen transfer
Adam, W
Saha-Möller, CR
Zhao, CG
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1999, 64 (20) : 7492 - 7497
[7] EPOXIDATION OF 2,3-DIMETHYLBENZOFURANS BY DIMETHYLDIOXIRANE
ADAM, W
BIALAS, J
HADJIARAPOGLOU, L
SAUTER, M
[J]. CHEMISCHE BERICHTE-RECUEIL, 1992, 125 (01): : 231 - 234
[8] Hydroxy group directivity in the epoxidation of chiral allylic alcohols: Control of diastereoselectivity through allylic strain and hydrogen bonding
Adam, W
Wirth, T
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1999, 32 (08) : 703 - 710
[9] Solvent effects in the regio- and diastereoselective epoxidations of acyclic allylic alcohols by dimethyldioxirane: Hydrogen bonding as evidence for a dipolar transition state
Adam, W
Smerz, AK
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1996, 61 (10) : 3506 - 3510
[10] SOLVENT EFFECTS IN THE DIMETHYLDIOXIRANE OXIDATION OF ALLYLIC ALCOHOLS - EVIDENCE FOR HYDROGEN-BONDING IN THE DIPOLAR TRANSITION-STATE OF OXYGEN-TRANSFER
ADAM, W
SMERZ, AK
[J]. TETRAHEDRON, 1995, 51 (47) : 13039 - 13044

← 1 2 3 4 5 6 7 8 9 10 →