Hydrogen-substituted osmium silylene complexes: Effect of charge localization on catalytic hydrosilation

被引：118

作者：

Hayes, PG

Beddie, C

Hall, MB ^{[1
]}

Waterman, R

Tilley, TD

机构：

[1] Texas A&M Univ, College Stn, TX 77843 USA

[2] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 02期

关键词：

D O I：

10.1021/ja057494q

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Addition of bulky primary silanes to the osmium benzyl compound, Cp*(iPr3P)OsCH2Ph, afforded two neutral hydrogen-substituted silylene complexes via activation of two Si-H bonds. These species have been structurally characterized, and their reactivity has been examined experimentally and computationally. Comparison of these neutral silylene complexes with their cationic analogue highlights the dramatic influence of charge distribution on the reaction chemistry of metal silylene complexes. Copyright © 2006 American Chemical Society.

引用

页码：428 / 429

页数：2

共 21 条

[1] A theoretical investigation of ruthenium-catalyzed alkene hydrosilation: Evidence to support an exciting new mechanistic proposal [J].