A high-throughput investigation of the role of pH, temperature, concentration, and time on the synthesis of hybrid inorganic-organic materials

被引:281
作者
Forster, PM
Stock, N
Cheetham, AK
机构
[1] Univ Kiel, Inst Anorgan Chem, D-24118 Kiel, Germany
[2] Univ Calif Santa Barbara, Mat Res Lab, Santa Barbara, CA 93106 USA
关键词
cobalt; high-throughput methods; hydrothermal synthesis; inorganic-organic hybrid materials; succinic acid;
D O I
10.1002/anie.200501766
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Figure Presented) Four reaction parameters and their effects on the formation of cobalt succinate phases were studied by high-throughput methods. In addition to identifying two new phases, we show that higher reaction temperatures lead to products containing less water, more basic conditions favor increasingly condensed M-O-M networks (see phase diagram), and depending on the reaction time the products are formed under either kinetic or thermodynamic control. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:7608 / 7611
页数:4
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