Synthesis, characterization and thermal properties of polymer/magnetite nanocomposites

被引：88

作者：

Dallas, Panagiotis ^{[1
]}

Georgakilas, Vasilios

Niarchos, Dimitrios

Komninou, Philomela

Kehagias, Thomas

Petridis, Dimitrios

机构：

[1] NCSR Demokritos, Inst Mat Sci, Athens 15310, Greece

[2] Aristotle Univ Thessaloniki, Dept Phys, Thessaloniki, Greece

来源：

NANOTECHNOLOGY | 2006年 / 17卷 / 08期

关键词：

D O I：

10.1088/0957-4484/17/8/043

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

A new procedure for the preparation of polymer/magnetic nanoparticle composites is described. Magnetite nanoparticles capped with methacrylate units were dispersed in a toluene solution of the monomer, and polymerization occurred after the addition of the initiator a'-a-azo-iso-butyronitrile at reflux temperature. The structural properties were determined by infrared spectroscopy, x-ray diffractometry and transmission electron microscopy. The thermal properties of the resulting nanocomposite were studied extensively with modulated differential scanning calorimetry. An increase in the glass transition temperature was observed after the incorporation of the nanoparticles.

引用

页码：2046 / 2053

页数：8

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