Phosphonium-borate nitterions, anionic phosphines, and dianionic phosphonium-dialkoxides via tetrahydrofuran ring-opening reactions

被引：100

作者：

Welch, GC ^{[1
]}

Masuda, JD ^{[1
]}

Stephan, DW ^{[1
]}

机构：

[1] Univ Windsor, Dept Chem & Biochem, Windsor, ON N9B 3P4, Canada

来源：

INORGANIC CHEMISTRY | 2006年 / 45卷 / 02期

关键词：

D O I：

10.1021/ic051713r

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Sterically demanding secondary phosphines and phosphides react with (THF)B(C6F5)(3) (THF = tetrahydrofuran) to give the THF ring-opened compounds [R2PHC4H8OB(C6F5)(3)] and [MeS2PC4H8OB(C6F5)(3)Li(THF)(2)] (Mes = C(6)H(2)AMe-2,4,6). These reactions also occur consecutively to give the double THF ring-opened compounds [MeS2P(C4H8OB(C6F5)(3))(2)][Li(THF)(4)] and [t-Bu2P(C4H8OB(C6F5)(3))(2-)Li].

引用

页码：478 / 480

页数：3

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