Is the bis-μ-oxo Cu2(III,III) state an intermediate in tyrosinase?

被引：54

作者：

Siegbahn, PEM ^{[1
]}

Wirstam, M

机构：

[1] Stockholm Univ, Stockholm Ctr Phys Astron & Biotechnol, Dept Phys, SCFAB, S-10691 Stockholm, Sweden

[2] Columbia Univ, Dept Chem, New York, NY 10027 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2001年 / 123卷 / 47期

关键词：

D O I：

10.1021/ja010829t

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：11819 / 11820

页数：2

共 26 条

[1] A NEW MIXING OF HARTREE-FOCK AND LOCAL DENSITY-FUNCTIONAL THEORIES [J].

BECKE, AD .

JOURNAL OF CHEMICAL PHYSICS, 1993, 98 (02) :1372-1377

[2] DENSITY-FUNCTIONAL THERMOCHEMISTRY .3. THE ROLE OF EXACT EXCHANGE [J].

BECKE, AD .

JOURNAL OF CHEMICAL PHYSICS, 1993, 98 (07) :5648-5652

[3] Ligand effects in the models and mimics of oxyhemocyanin and oxytyrosinase. A density functional study of reversible dioxygen binding and reversible O-O bond cleavage [J].

Berces, A .

INORGANIC CHEMISTRY, 1997, 36 (21) :4831-4837

[4] Ab initio study of the mechanism of the binding of triplet O-2 to hemocyanin [J].

Bernardi, F ;

Bottoni, A ;

Casadio, R ;

Fariselli, P ;

Rigo, A .

INORGANIC CHEMISTRY, 1996, 35 (18) :5207-5212

[5] Cationic species can be produced in soluble methane monooxygenase-catalyzed hydroxylation reactions; radical intermediates are not formed [J].

Choi, SY ;

Eaton, PE ;

Kopp, DA ;

Lippard, SJ ;

Newcomb, M ;

Shen, RN .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (51) :12198-12199

[6] Theoretical study of the interconversion of O2-binding dicopper complexes [J].

Flock, M ;

Pierloot, K .

JOURNAL OF PHYSICAL CHEMISTRY A, 1999, 103 (01) :95-102

[7] Reversible cleavage and formation of the dioxygen O-O band within a dicopper complex [J].

Halfen, JA ;

Mahapatra, S ;

Wilkinson, EC ;

Kaderli, S ;

Young, VG ;

Que, L ;

Zuberbuhler, AD ;

Tolman, WB .

SCIENCE, 1996, 271 (5254) :1397-1400

[8] Oxygenation of phenols to catechols by a (μ-η2:η2-peroxo)dicopper(II) complex:: Mechanistic insight into the phenolase activity of tyrosinase [J].

Itoh, S ;

Kumei, H ;

Taki, M ;

Nagatomo, S ;

Kitagawa, T ;

Fukuzumi, S .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (27) :6708-6709

[9] COPPER-DIOXYGEN COMPLEXES - INORGANIC AND BIOINORGANIC PERSPECTIVES [J].

KITAJIMA, N ;

MOROOKA, Y .

CHEMICAL REVIEWS, 1994, 94 (03) :737-757

[10] A NEW MODEL FOR DIOXYGEN BINDING IN HEMOCYANIN - SYNTHESIS, CHARACTERIZATION, AND MOLECULAR-STRUCTURE OF THE MU-ETA-2-ETA-2 PEROXO DINUCLEAR COPPER(II) COMPLEXES, [CU(HB(3,5-R2PZ)3)]2(O2) (R = ISO-PR AND PH) [J].

KITAJIMA, N ;

FUJISAWA, K ;

FUJIMOTO, C ;

MOROOKA, Y ;

HASHIMOTO, S ;

KITAGAWA, T ;

TORIUMI, K ;

TATSUMI, K ;

NAKAMURA, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (04) :1277-1291

← 1 2 3 →