A new strategy to reach highly extended and quinonoid tetrathiafulvalene (TTF) derivatives

被引：29

作者：

Gautier, N

Mercier, N

Riou, A

Gorgues, A

Hudhomme, P

机构：

[1] CNRS, UMR 6501, F-49045 Angers, France

[2] Organ Synth Lab, CNRS, UMR 6513, F-44322 Nantes 03, France

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 33期

关键词：

D O I：

10.1016/S0040-4039(99)01162-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

2,3-Bis(bromomethyl)TTFs 4 are used as precursors of 2,3-dimethylene-[2H]-TTFs 5 to reach cycloadducts of high synthetic interest via a [4+2] cycloaddition with quinonic derivatives. Subsequent Horner-Wadsworth-Emmons olefinations with a 1,3-dithiole phosphonate anion afforded highly extended and sulfur-rich analogs of tetrathiafulvalene 1. (C) 1999 Published by Elsevier Science Ltd. All rights reserved.

引用

页码：5997 / 6000

页数：4

共 28 条

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