Bromoiodinanes with an I(III)-Br bond: preparation, X-ray crystallography and reactivity as electrophilic brominating agents

被引:49
作者
Braddock, DC [1 ]
Cansell, G
Hermitage, SA
White, AJP
机构
[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AZ, England
[2] GlaxoSmithKline Ltd, Med Res Ctr, Stevenage SG1 2NY, Herts, England
关键词
D O I
10.1039/b600455e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Bromoiodinanes - conveniently and directly prepared from iodobenzenecarbinols and N-bromosuccinimide, and characterised for the first time crystallographically - act as electrophilic bromine donors.
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页码:1442 / 1444
页数:3
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