Unusual structure and reactivity of a homoleptic "super-ate" complex of iron:: Implications for Grignard additions, cross-coupling reactions, and the Kharasch deconjugation

被引：137

作者：

Fürstner, A ^{[1
]}

Krause, H ^{[1
]}

Lehmann, CW ^{[1
]}

机构：

[1] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 03期

关键词：

ate complexes; cross-coupling; Grignard reaction; iron; single-electron transfer;

D O I：

10.1002/anie.200502859

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The additional molecule of methyllithium present in [(Me 4Fe)(MeLi)][Li(OEt2)]2 (1), the first structurally characterized ate complex of FeII bearing only alkyl substituents without any further stabilizing ligands (see picture: Fe: magenta; Li: cyan; O: red; C and H: gray), is a particularly remarkable structural feature and contributes to the fascinating reactivity profile of 1 in the title reactions. (Chemical Equation Presented). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：440 / 444

页数：5

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