Unusual structure and reactivity of a homoleptic "super-ate" complex of iron:: Implications for Grignard additions, cross-coupling reactions, and the Kharasch deconjugation

被引：137

作者：

Fürstner, A ^{[1
]}

Krause, H ^{[1
]}

Lehmann, CW ^{[1
]}

机构：

[1] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 03期

关键词：

ate complexes; cross-coupling; Grignard reaction; iron; single-electron transfer;

D O I：

10.1002/anie.200502859

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The additional molecule of methyllithium present in [(Me 4Fe)(MeLi)][Li(OEt2)]2 (1), the first structurally characterized ate complex of FeII bearing only alkyl substituents without any further stabilizing ligands (see picture: Fe: magenta; Li: cyan; O: red; C and H: gray), is a particularly remarkable structural feature and contributes to the fascinating reactivity profile of 1 in the title reactions. (Chemical Equation Presented). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：440 / 444

页数：5

共 85 条

[51] Kerber R., 1995, COMPREHENSIVE ORGANO, V7, P101
[52] Factors determining the course and mechanisms of Grignard reactions. II. The effect of metallic compounds on the reaction between isophorone and methylmagnesium bromide
Kharasch, MS
Tawney, PO
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1941, 63 : 2308 - 2315
[53] MAGNETIC-PROPERTIES DIAGNOSTIC FOR THE EXISTENCE OF IRON(II)-IRON(II) BONDS IN DINUCLEAR COMPLEXES WHICH DERIVE FROM STEPWISE INSERTION REACTIONS ON UNSUPPORTED IRON-ARYL BONDS
KLOSE, A
SOLARI, E
FLORIANI, C
CHIESIVILLA, A
RIZZOLI, C
RE, N
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (20) : 9123 - 9135
[54] ELECTRON-TRANSFER MECHANISMS FOR ORGANOMETALLIC INTERMEDIATES IN CATALYTIC REACTIONS
KOCHI, JK
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1974, 7 (10) : 351 - 360
[55] THE KHARASCH REAGENT - REGIOSELECTIVE GENERATION OF DIENOL ETHERS FROM ENONES
KRAFFT, ME
HOLTON, RA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (24) : 7619 - 7621
[56] PREPARATION OF A NEW, HIGHLY REACTIVE FORM OF IRON(0) AND ITS USE IN DEPROTONATION OF CARBONYL-COMPOUNDS
KRAFT, ME
HOLTON, RA
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1984, 49 (19) : 3669 - 3670
[57] Total synthesis of amphidinolide X
Lepage, O
Kattnig, E
Fürstner, A
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (49) : 15970 - 15971
[58] Cross-coupling of alkyl halides with aryl Grignard reagents catalyzed by a low-valent iron complex
Martin, R
Fürstner, A
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (30) : 3955 - 3957
[59] Martin R., 2004, ANGEW CHEM, V116, P4045
[60] Connective synthesis of spirovetivanes:: Total synthesis of (±)-agarospirol, (±)-hinesol and (±)-α-vetispirene
Maulide, N
Vanherck, JC
Markó, IE
[J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2004, 2004 (19) : 3962 - 3967

← 1 2 3 4 5 6 7 8 9 →