Layered titanate nanostructures and their derivatives as negative electrode materials for lithium-ion batteries

被引：86

作者：

Hong, Zhensheng ^{[1
]}

Wei, Mingdeng ^{[1
]}

机构：

[1] Fuzhou Univ, Inst Adv Energy Mat, Fuzhou 350002, Fujian, Peoples R China

来源：

JOURNAL OF MATERIALS CHEMISTRY A | 2013年 / 1卷 / 14期

基金：

中国国家自然科学基金; 美国国家科学基金会;

关键词：

TIO2; MESOCRYSTALS; RATE PERFORMANCE; STORAGE; RUTILE; ANODE; INTERCALATION; NANOTUBES; NANOWIRES; LI4TI5O12; ANATASE;

D O I：

10.1039/c2ta01312f

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Ti-based materials have been intensively investigated and considered as good potential negative electrode materials for lithium-ion batteries (LIBs) due to their high safety, superior rate capability and excellent cyclic stability. This feature article summarizes the recent progress of a new class of layered titanate (H2TinO2n+1 center dot H2O) nanostructures and their derivatives, including TiO2 polymorphs, novel titanate nanostructures of Zn2Ti3O8, Li2MTi3O8 (M = Co, Zn, Mg) and Li4Ti5O12, as high performance negative electrode materials for LIBs. The effects of the composition, crystal structure and morphology on lithium-ion intercalation properties are highlighted and analyzed.

引用

页码：4403 / 4414

页数：12

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