Solid-supported green synthesis of substituted hydrocinnamic esters by focused microwave irradiation

被引:19
作者
Kumar, V [1 ]
Sharma, A [1 ]
Sinha, AK [1 ]
机构
[1] Inst Himalayan Bioresource Technol, Nat Plant Prod Div, Palampur 176061, Himachal Prades, India
关键词
D O I
10.1002/hlca.200690049
中图分类号
O6 [化学];
学科分类号
0703 [化学];
摘要
An efficient chemoselective hydrogenation protocol for substituted cinnamic esters is developed for the synthesis in quantitative yield of corresponding bioactive dilrydrocinnamic esters with solid-supported palladium chloride/ammonium formate (cat.) in HCOOH/H2O 1:2 as a hydrogenating agent under focused-microwave irradiation for 10 min.
引用
收藏
页码:483 / 495
页数:13
相关论文
共 52 条
[1]
Anastas P. T., 1998, GREEN CHEM THEORY PR
[2]
[Anonymous], 1994, DICT NATURAL PRODUCT
[3]
*AS RES CTR, 1987, HDB PR3T N7R SPECTR
[4]
Microwave-induced organic reaction enhancement (MORE) chemistry. Part 13. Microwave-assisted rapid and simplified hydrogenation [J].
Banik, BK ;
Barakat, KJ ;
Wagle, DR ;
Manhas, MS ;
Bose, AK .
JOURNAL OF ORGANIC CHEMISTRY, 1999, 64 (16) :5746-5753
[5]
Berthold H, 2002, SYNTHESIS-STUTTGART, P1607
[6]
Bose AK, 1997, CHEMTECH, V27, P18
[7]
BOSE AK, 1993, SYNLETT, P575
[8]
A green and selective reduction of aldehydes [J].
Bryson, TA ;
Jennings, JM ;
Gibson, JM .
TETRAHEDRON LETTERS, 2000, 41 (19) :3523-3526
[9]
Recent advances in solventless organic reactions: towards benign synthesis with remarkable versatility [J].
Cave, GWV ;
Raston, CL ;
Scott, JL .
CHEMICAL COMMUNICATIONS, 2001, (21) :2159-2169
[10]
Reduction of conjugate double bonds with trichlorosilane [J].
Chauhan, M ;
Boudjouk, P .
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 2000, 78 (11) :1396-1398