Shining light on a pentacene derivative: The role of photoinduced cycloadditions

被引：126

作者：

Coppo, P ^{[1
]}

Yeates, SG ^{[1
]}

机构：

[1] Univ Manchester, Sch Chem, Organ Mat Innovat Ctr, Manchester M13 9PL, Lancs, England

来源：

ADVANCED MATERIALS | 2005年 / 17卷 / 24期

关键词：

D O I：

10.1002/adma.200501471

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Dimerization in a "butterfly" fashion: a soluble pentacene derivative undergoes photoinduced dimerization upon exposure to UV and visible light, both in solution and in the solid state. This pathway of degradation does not involve oxygen or moisture. Strategies to limit the damage require use of highly crystalline thin films or storage as a solution in benzene, which cooperatively interacts with the pentacene core, hampering the dimerization process.

引用

页码：3001 / +

页数：6

共 37 条

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