SCR of NOx by NH3;
Ag-based catalysts;
activity enhancement;
hydrogen admixture;
D O I:
10.1023/B:CATL.0000019340.51510.ba
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
Addition of H-2 to a NO/NH3/O-2/H2O feed for selective catalytic reduction of nitrogen oxide over Ag/Al2O3 catalysts causes an unusual enhancement of activity, e.g., the marginal activity (< 10%) of 1 wt% Ag impregnated on gamma-Al2O3 or mesoporous Al2O3 modi. cations is boosted to nearly 100% over a broad temperature range from 200 to 550 degrees C at a space velocity of 30,000 cm(3) g(-1) h(-1)). Contrary, silver on SiO2 or alpha-Al2O3 shows no improvement of activity in the presence of H-2. The effect is tentatively attributed to a higher percentage of intermediary nano-sized Ag clusters on high-surface area Al2O3 in the presence of hydrogen. This promotes oxygen activation and hence NO oxidation to reactive intermediate nitrite species. The required dispersion of Ag cannot be stabilized on SiO2 or alpha-Al2O3.
机构:
Nagoya Univ, Dept Appl Chem, Grad Sch Engn, Chikusa Ku, Nagoya, Aichi 4648603, JapanNagoya Univ, Dept Appl Chem, Grad Sch Engn, Chikusa Ku, Nagoya, Aichi 4648603, Japan
Shibata, J
;
Shimizu, K
论文数: 0引用数: 0
h-index: 0
机构:Nagoya Univ, Dept Appl Chem, Grad Sch Engn, Chikusa Ku, Nagoya, Aichi 4648603, Japan
Shimizu, K
;
Satokawa, S
论文数: 0引用数: 0
h-index: 0
机构:Nagoya Univ, Dept Appl Chem, Grad Sch Engn, Chikusa Ku, Nagoya, Aichi 4648603, Japan
Satokawa, S
;
Satsuma, A
论文数: 0引用数: 0
h-index: 0
机构:Nagoya Univ, Dept Appl Chem, Grad Sch Engn, Chikusa Ku, Nagoya, Aichi 4648603, Japan
Satsuma, A
;
Hattori, T
论文数: 0引用数: 0
h-index: 0
机构:Nagoya Univ, Dept Appl Chem, Grad Sch Engn, Chikusa Ku, Nagoya, Aichi 4648603, Japan
机构:
Nagoya Univ, Dept Appl Chem, Grad Sch Engn, Chikusa Ku, Nagoya, Aichi 4648603, JapanNagoya Univ, Dept Appl Chem, Grad Sch Engn, Chikusa Ku, Nagoya, Aichi 4648603, Japan
Shibata, J
;
Shimizu, K
论文数: 0引用数: 0
h-index: 0
机构:Nagoya Univ, Dept Appl Chem, Grad Sch Engn, Chikusa Ku, Nagoya, Aichi 4648603, Japan
Shimizu, K
;
Satokawa, S
论文数: 0引用数: 0
h-index: 0
机构:Nagoya Univ, Dept Appl Chem, Grad Sch Engn, Chikusa Ku, Nagoya, Aichi 4648603, Japan
Satokawa, S
;
Satsuma, A
论文数: 0引用数: 0
h-index: 0
机构:Nagoya Univ, Dept Appl Chem, Grad Sch Engn, Chikusa Ku, Nagoya, Aichi 4648603, Japan
Satsuma, A
;
Hattori, T
论文数: 0引用数: 0
h-index: 0
机构:Nagoya Univ, Dept Appl Chem, Grad Sch Engn, Chikusa Ku, Nagoya, Aichi 4648603, Japan