The asymmetric hetero-Diels-Alder reaction and addition of allylic organometallics to 10-N,N-dicyclohexylsulphamoyl(2R)-isobornyl glyoxylate

被引：12

作者：

Czapla, A

Chajewski, A

Kiegiel, K

Bauer, T

Wielogorski, Z

Urbanczyk-Lipkowska, Z

Jurczak, J

机构：

[1] Univ Warsaw, Dept Chem, PL-02093 Warsaw, Poland

[2] Polish Acad Sci, Inst Organ Chem, PL-01224 Warsaw, Poland

来源：

TETRAHEDRON-ASYMMETRY | 1999年 / 10卷 / 11期

关键词：

D O I：

10.1016/S0957-4166(99)00212-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The recent development of very effective chiral auxiliaries has led to the design of 10-N,N-dicyclohexylsulphamoyl-(R)-isoborneol, which is similar to Oppolzer's (2R)-bornane-10,2-sultam but less effective on account of a less rigid structure. 10-N,N-Dicyclohexylsulphamoyl-(R)-isobornyl glyoxylate was examined in Diels-Alder and organometallic addition reactions. The results obtained were compared with those achieved by application of N-glyoxyloyl-(2R)-bornane-10,2-sultam. (C) 1999 Elsevier Science Ltd. All rights reserved.

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页码：2101 / 2111

页数：11

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