Simplifying Iron-Phosphine Catalysts for Cross-Coupling Reactions

被引：96

作者：

Bedford, Robin B. ^{[1
]}

Carter, Emma ^{[2
]}

Cogswell, Paul M. ^{[1
]}

Gower, Nicholas J. ^{[1
]}

Haddow, Mairi F. ^{[1
]}

Harvey, Jeremy N. ^{[1
]}

Murphy, Damien M. ^{[2
]}

Neeve, Emily C. ^{[1
]}

Nunn, Joshua ^{[1
]}

机构：

[1] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England

[2] Cardiff Univ, Sch Chem, Cardiff CF10 3TB, S Glam, Wales

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 04期

基金：

英国工程与自然科学研究理事会;

关键词：

alkyl halides; catalysis; cross-coupling; iron; phosphine ligands; ALKYL-HALIDES; GRIGNARD-REAGENTS; COMPLEXES;

D O I：

10.1002/anie.201207868

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Any old iron? Iron catalysts based on the widely available diphosphine ligand bis(diphenylphosphino)ethane have not previously fared particularly well in iron-catalyzed cross-coupling processes. However, this turns out not to be due to any inherently poor performance associated with the ligand, but rather the need to form a bis-chelate complex, either before or during the formation of an active FeI species. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：1285 / 1288

页数：4

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