trans-allylstannylation of certain acetylenes catalysed by ZrCl4

被引：49

作者：

Asao, N ^{[1
]}

Matsukawa, Y ^{[1
]}

Yamamoto, Y ^{[1
]}

机构：

[1] TOHOKU UNIV,DEPT CHEM,GRAD SCH SCI,SENDAI,MIYAGI 98077,JAPAN

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 13期

关键词：

D O I：

10.1039/cc9960001513

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The trans-allylstannylation of simple acetylenes 1 is catalysed by ZrCl4 to produce the corresponding alkenylstannanes 3 (or alkenes 4 upon protonolysis of the C-Sn bond) in a regio- and stereo-selective manner.

引用

页码：1513 / 1514

页数：2

共 10 条

[1] CARBOINDATION OF ALKYNES - REGIOSELECTIVE AND STEREOSELECTIVE ALLYLATION OF CARBON-CARBON TRIPLE BONDS OF ALKYNOLS BY ALLYLIC INDIUM REAGENTS
ARAKI, S
IMAI, A
SHIMIZU, K
YAMADA, M
MORI, A
BUTSUGAN, Y
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1995, 60 (06) : 1841 - 1847
[2] LEWIS-ACID CATALYZED TRANS-HYDROSTANNYLATION OF ACETYLENES
ASAO, N
LIU, JX
SUDOH, T
YAMAMOTO, Y
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (23) : 2405 - 2406
[3] PD-CATALYZED COUPLING REACTION OF ACETYLENES, IODOTRIMETHYLSILANE, AND ORGANOZINC REAGENTS FOR THE STEREOSELECTIVE SYNTHESIS OF VINYLSILANES
CHATANI, N
AMISHIRO, N
MORII, T
YAMASHITA, T
MURAI, S
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1995, 60 (06) : 1834 - 1840
[4] Knochel P., 1995, COMPREHENSIVE ORGA 2, V11, P159
[5] BIMETALLIC CATALYTIC-SYSTEMS CONTAINING TI, ZR, NI, AND PD - THEIR APPLICATIONS TO SELECTIVE ORGANIC SYNTHESES
NEGISHI, E
[J]. PURE AND APPLIED CHEMISTRY, 1981, 53 (12) : 2333 - 2356
[6] NORMANT JF, 1981, SYNTHESIS-STUTTGART, P841
[7] INTRAMOLECULAR, STOICHIOMETRIC (LI, MG, ZN) AND CATALYTIC (NI, PD, PT) METALLO-ENE REACTIONS IN ORGANIC-SYNTHESIS
OPPOLZER, W
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1989, 28 (01): : 38 - 52
[8] COPPER-CATALYZED C-C BOND FORMATION REACTION OF ALLYLZIRCONATION PRODUCTS OF ALKYNES
TAKAHASHI, T
KOTORA, M
KASAI, K
SUZUKI, N
[J]. TETRAHEDRON LETTERS, 1994, 35 (31) : 5685 - 5688
[9] FORMAL HYDROALLYLATION OF CARBON-CARBON TRIPLE BONDS VIA TANTALUM-ALKYNE COMPLEXES - STEREOSELECTIVE PREPARATION OF 1,4-DIENES
TAKAI, K
YAMADA, M
ODAKA, H
UTIMOTO, K
FUJII, T
FURUKAWA, I
[J]. CHEMISTRY LETTERS, 1995, (04) : 315 - 316
[10] SELECTIVE REACTIONS USING ALLYLIC METALS
YAMAMOTO, Y
ASAO, N
[J]. CHEMICAL REVIEWS, 1993, 93 (06) : 2207 - 2293

← 1 →