Efficient Rh(I)-Catalyzed Direct Arylation and Alkenylation of Arene C-H Bonds via Decarbonylation of Benzoic and Cinnamic Anhydrides

被引：95

作者：

Jin, Weiwei ^{[1
,2
]}

Yu, Zhengkun ^{[1
]}

He, Wei ^{[1
]}

Ye, Wenjing ^{[1
]}

Xiao, Wen-Jing ^{[2
]}

机构：

[1] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China

[2] Cent China Normal Univ, Key Lab Pesticide & Chem Biol, Minist Educ, Coll Chem, Wuhan 430079, Hubei, Peoples R China

来源：

ORGANIC LETTERS | 2009年 / 11卷 / 06期

基金：

中国国家自然科学基金;

关键词：

CATALYZED DIRECT ARYLATION; PYRIDINE-N-OXIDES; UNACTIVATED ARENES; CARBOXYLIC-ACIDS; DIETHYL AZODICARBOXYLATE; DIRECT FUNCTIONALIZATION; SELECTIVE ALKENYLATION; COUPLING REACTION; TERMINAL ALKYNES; BORONIC ACIDS;

D O I：

10.1021/ol9000729

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Efficient rhodium(I)-catalyzed regioselective direct arylation and alkenylation of aromatic C-H bonds has been realized with aromatic carboxylic and cinnamic anhydrides as the coupling partners via decarbonylation and C-H activation under phosphine-free conditions.

引用

页码：1317 / 1320

页数：4

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