CO sensing with SnO2-based thick film sensors:: Surface state model for conductance responses during thermal-modulation

被引:26
作者
Fort, A.
Rocchi, S.
Serrano-Santos, M. B.
Mugnaini, M.
Vignoli, V.
Atrei, A.
Spinicci, R.
机构
[1] Univ Siena, Dipartimento Ingn Informaz, I-53100 Siena, Italy
[2] Univ Siena, Dipartimento Sci & Tecnol Chim & Biosistemi, I-53100 Siena, Italy
[3] Univ Florence, Dipartimento Energet, I-50139 Florence, Italy
关键词
electronic nose; metal oxide sensors; temperature modulations; grey-box model; CO;
D O I
10.1016/j.snb.2005.11.070
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
There exists a strong interest in developing simplified models able to predict the SnO2 sensor response and aiming at a better comprehension of the mechanisms involved with sensing operation. In this paper, a simple grey-box model is proposed for predicting, with a good approximation (r.m.s. error < 10%). the behavior of some commercial SnO2-based sensors in presence of oxygen and a reducing gas (CO) during fast temperature variations. Auger electron spectroscopy (AES) permitted to highlight differences in the surface composition of the sensors after extended operation time. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:43 / 48
页数:6
相关论文
共 13 条
[1]   Conduction model of metal oxide gas sensors [J].
Barsan, N ;
Weimar, U .
JOURNAL OF ELECTROCERAMICS, 2001, 7 (03) :143-167
[2]   Simulation of thin film gas sensors kinetics [J].
Brynzari, V ;
Korotchenkov, G ;
Dmitriev, S .
SENSORS AND ACTUATORS B-CHEMICAL, 1999, 61 (1-3) :143-153
[3]   Temperature profile investigation of SnO2 sensors for CO detection enhancement [J].
Burresi, A ;
Fort, A ;
Rocchi, S ;
Santos, MBS ;
Ulivieri, N ;
Vignoli, V .
IEEE TRANSACTIONS ON INSTRUMENTATION AND MEASUREMENT, 2005, 54 (01) :79-86
[4]  
CLIFFORD PK, 1983, P 1 INT M CHEM SENS
[5]   Surface state trapping models for SnO2-based microhotplate sensors [J].
Ding, JH ;
McAvoy, TJ ;
Cavicchi, RE ;
Semancik, S .
SENSORS AND ACTUATORS B-CHEMICAL, 2001, 77 (03) :597-613
[6]   Response model for thermally modulated tin oxide-based microhotplate gas sensors [J].
Ionescu, R ;
Llobet, E ;
Al-Khalifa, S ;
Gardner, JW ;
Vilanova, X ;
Brezmes, J ;
Correig, X .
SENSORS AND ACTUATORS B-CHEMICAL, 2003, 95 (1-3) :203-211
[7]   Optimization of temperature programmed sensing for gas identification using micro-hotplate sensors [J].
Kunt, TA ;
McAvoy, TJ ;
Cavicchi, RE ;
Semancik, S .
SENSORS AND ACTUATORS B-CHEMICAL, 1998, 53 (1-2) :24-43
[8]   Multicomponent Gas Mixture Analysis Using a Single Tin Oxide Sensor and Dynamic Pattern Recognition [J].
Llobet, Eduard ;
Ionescu, Radu ;
Al-Khalifa, Sherzad ;
Brezmes, Jesus ;
Vilanova, Xavier ;
Correig, Xavier ;
Barsan, Nicolae ;
Gardner, Julian W. .
IEEE SENSORS JOURNAL, 2001, 1 (03) :207-213
[9]  
*MATLAB, 1994, OPT TOOLB
[10]   TIN DIOXIDE GAS SENSORS .1. ASPECTS OF THE SURFACE-CHEMISTRY REVEALED BY ELECTRICAL CONDUCTANCE VARIATIONS [J].
MCALEER, JF ;
MOSELEY, PT ;
NORRIS, JOW ;
WILLIAMS, DE .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1987, 83 :1323-1346