Optimization of the rice bran oil deacidification process by liquid-liquid extraction

被引:45
作者
Rodrigues, CEC [1 ]
Onoyama, MM [1 ]
Meirelles, AJA [1 ]
机构
[1] Univ Estadual Campinas, LASEFI, Fac Engn Alimentos, BR-13083862 Campinas, SP, Brazil
基金
巴西圣保罗研究基金会;
关键词
liquid-liquid extraction; deacidification; rice bran oil; oryzanol; tocopherols; response surface analysis; UNIQUAC;
D O I
10.1016/j.jfoodeng.2005.02.004
中图分类号
TQ [化学工业];
学科分类号
0817 [化学工程与技术];
摘要
The present paper reports the process variable influence on the losses/transfer of fatty compounds during the deacidification process of rice bran oil by liquid-liquid extraction. The influence of process variables such as free fatty acid concentration in the oil, water content in the ethanolic solvent and oil:solvent mass ratio, were analyzed using the response surface methodology, having the aim to maximize the transfer of free fatty acids and minimize the losses of neutral oil plus minor compounds. In addition, the UNIQUAC equation was used to predict the transfer/losses of fatty and nutraceutical compounds to the alcohol phase. Both methodologies, the mathematical model from non-linear multiple regression and the UNIQUAC model, presented good agreement with the experimental data. (c) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码:370 / 378
页数:9
相关论文
共 34 条
[1]
ANTONIOSI NR, 1995, CHROMATOGRAPHIA, V40, P557, DOI 10.1007/BF02290268
[2]
*AOCS, 1988, OFF METH REC PRACT A, V1
[3]
Liquid-liquid equilibrium for systems of canola oil, oleic acid, and short-chain alcohols [J].
Batista, E ;
Monnerat, S ;
Kato, K ;
Stragevitch, L ;
Meirelles, AJA .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1999, 44 (06) :1360-1364
[4]
Prediction of liquid-liquid equilibrium for systems of vegetable oils, fatty acids, and ethanol [J].
Batista, E ;
Monnerat, S ;
Stragevitch, L ;
Pina, CG ;
Gonçalves, CB ;
Meirelles, AJA .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1999, 44 (06) :1365-1369
[5]
BHATTACHARYYA AC, 1987, OLEAGINEUX, V42, P431
[6]
Box G.E., 1978, STAT EXPT
[7]
PHYSICAL REFINING OF EDIBLE OILS [J].
CVENGROS, J .
JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1995, 72 (10) :1193-1196
[8]
Eitenmiller RR, 1997, FOOD TECHNOL-CHICAGO, V51, P78
[9]
Liquid-liquid equilibrium data for the system corn oil plus oleic acid plus ethanol plus water at 298.15 K [J].
Gonçalves, CB ;
Batista, E ;
Meirelles, AJA .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2002, 47 (03) :416-420
[10]
Water degumming of rice bran oil: a response surface approach [J].
Indira, TN ;
Hemavathy, J ;
Khatoon, S ;
Krishna, AGG ;
Bhattacharya, S .
JOURNAL OF FOOD ENGINEERING, 2000, 43 (02) :83-90