New star-shaped luminescent triarylamines: Synthesis, thermal, photophysical, and electroluminescent characteristics

被引：99

作者：

Thomas, KRJ

Lin, JT ^{[1
]}

Tao, YT

Ko, CW

机构：

[1] Acad Sinica, Inst Chem, Taipei 115, Taiwan

[2] Natl Cent Univ, Dept Chem, Chungli 320, Taiwan

来源：

CHEMISTRY OF MATERIALS | 2002年 / 14卷 / 03期

关键词：

D O I：

10.1021/cm010976q

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A series of 3,6-disubstituted carbazole and 1,3,5-trisubstituted benzene derivatives incorporating thienyl aromatic (phenyl, fluorenyl, and carbazolyl) conjugation and end-capped diphenylamine were synthesized by iterative C-N and C-C coupling procedures. The carbazole derivatives emit blue light and the star-shaped benzene derivatives emit either blue or bluish green color depending on the conjugation segment. In general, they possess high glass transition temperatures (>120 degreesC) and decomposition temperatures (> 520 degreesC). Double-layer organic light-emitting devices were successfully fabricated using these novel molecules as hole-transporting and emitting materials. Devices of the configuration ITO/HTM/TPBI/Mg:Ag display blue to green emission from the HTM layer while in the devices of the configuration ITO/HTM/Alq(3)/Mg:Ag, a typical green emission from the Alq(3) layer was observed.

引用

页码：1354 / 1361

页数：8

共 79 条

[31] Synthesis of octasubstituted cyclooctatetraenes and their use as electron transporters in organic light emitting diodes [J].