Phosphite-derivatized ruthenium-carbohydrate complexes in the catalytic hydration of nitriles

被引：21

作者：

Ashraf, Shaheen M. ^{[1
]}

Berger, Isabella ^{[1
]}

Nazarov, Alexey A. ^{[1
,2
]}

Hartinger, Christian G. ^{[1
,2
]}

Koroteev, Mikhail P. ^{[3
]}

Nifant'ev, Eduard E. ^{[3
]}

Keppler, Bernhard K. ^{[1
]}

机构：

[1] Univ Vienna, Inst Inorgan Chem, A-1090 Vienna, Austria

[2] Ecole Polytech Fed Lausanne, Inst Sci & Ingn Chim, CH-1015 Lausanne, Switzerland

[3] Moscow State Pedag Univ, Dept Chem, Moscow 119021, Russia

来源：

CHEMISTRY & BIODIVERSITY | 2008年 / 5卷 / 08期

关键词：

D O I：

10.1002/cbdv.200890151

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The synthesis of metal complexes with bioligands is one option to introduce chirally defined ligands to catalysts. Herein, file hydration of nitriles to the corresponding carboxamides by use of ruthenium(H) complexes is described, which were obtained by attaching derivatives of the 3,5,6-bicyclophosphite-alpha-D-glucofuranoside ligand.

引用

页码：1640 / 1644

页数：5

共 29 条

[1] Classical and non-classical ruthenium-based anticancer drugs: Towards targeted chemotherapy [J].

Ang, Wee Han ;

Dyson, Paul J. .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2006, (20) :4003-4018

[2]

ASHRAF SM, 2008, CHEM BIODIV IN PRESS, V5

[3] In Vitro Anticancer Activity and Biologically Relevant Metabolization of Organometallic Ruthenium Complexes with Carbohydrate-Based Ligands [J].

Berger, Isabella ;

Hanif, Muhammad ;

Nazarov, Alexey A. ;

Hartinger, Christian G. ;

John, Roland O. ;

Kuznetsov, Maxim L. ;

Groessl, Michael ;

Schmitt, Frederic ;

Zava, Olivier ;

Biba, Florian ;

Arion, Vladimir B. ;

Galanski, Markus ;

Jakupec, Michael A. ;

Juillerat-Jeanneret, Lucienne ;

Dyson, Paul J. ;

Keppler, Bernhard K. .

CHEMISTRY-A EUROPEAN JOURNAL, 2008, 14 (29) :9046-9057

[4] Organometallic chemistry in aqueous solution.: Hydration of nitriles to amides catalyzed by a water-soluble molybdocene, (MeCp)2Mo(OH)(H2O)+ [J].

Breno, KL ;

Pluth, MD ;

Tyler, DR .

ORGANOMETALLICS, 2003, 22 (06) :1203-1211

[5] METAL-CATALYZED HYDRATION OF PHENANTHROLINE NITRILE [J].

BRESLOW, R ;

FAIRWEAT.R ;

KEANA, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1967, 89 (09) :2135-&

[6]

Bruneau C, 2004, TOP ORGANOMETAL CHEM, V11, P125

[7] SYNTHESIS AND BASE HYDROLYSIS OF PENTAAMMINE N,N-DIMETHYLFORMAMIDE AND ACETONITRILE COMPLEXES OF RH(III) AND IR(III) [J].

CURTIS, NJ ;

SARGESON, AM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (03) :625-630

[8] Ligands derived from carbohydrates for asymmetric catalysis [J].

Diéguez, M ;

Pàmies, OP ;

Claver, C .

CHEMICAL REVIEWS, 2004, 104 (06) :3189-3215

[9] The hydration of nitriles catalyzed by water-soluble rhodium complexes [J].

Djoman, MCKB ;

Ajjou, AN .

TETRAHEDRON LETTERS, 2000, 41 (25) :4845-4849

[10] Metal-based antitumour drugs in the post genomic era [J].

Dyson, PJ ;

Sava, G .

DALTON TRANSACTIONS, 2006, (16) :1929-1933

← 1 2 3 →