Phosphite-derivatized ruthenium-carbohydrate complexes in the catalytic hydration of nitriles

被引：21

作者：

Ashraf, Shaheen M. ^{[1
]}

Berger, Isabella ^{[1
]}

Nazarov, Alexey A. ^{[1
,2
]}

Hartinger, Christian G. ^{[1
,2
]}

Koroteev, Mikhail P. ^{[3
]}

Nifant'ev, Eduard E. ^{[3
]}

Keppler, Bernhard K. ^{[1
]}

机构：

[1] Univ Vienna, Inst Inorgan Chem, A-1090 Vienna, Austria

[2] Ecole Polytech Fed Lausanne, Inst Sci & Ingn Chim, CH-1015 Lausanne, Switzerland

[3] Moscow State Pedag Univ, Dept Chem, Moscow 119021, Russia

来源：

CHEMISTRY & BIODIVERSITY | 2008年 / 5卷 / 08期

关键词：

D O I：

10.1002/cbdv.200890151

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The synthesis of metal complexes with bioligands is one option to introduce chirally defined ligands to catalysts. Herein, file hydration of nitriles to the corresponding carboxamides by use of ruthenium(H) complexes is described, which were obtained by attaching derivatives of the 3,5,6-bicyclophosphite-alpha-D-glucofuranoside ligand.

引用

页码：1640 / 1644

页数：5

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