Ruthenium catalysis in organic synthesis

被引:84
作者
Murahashi, SI
Takaya, H
Naota, T
机构
[1] Okayama Univ Sci, Dept Appl Chem, Okayama 7000005, Japan
[2] Osaka Univ, Grad Sch Engn Sci, Dept Chem, Osaka 5608531, Japan
关键词
D O I
10.1351/pac200274010019
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Ruthenium, rhodium, iridium, and rhenium hydride complexes are highly useful redox Lewis acid and base catalysts. Various substrates bearing hetero atoms are activated by these catalysts and undergo reactions with either nucleophiles or electrophiles under neutral conditions. These types of catalytic reactions are described together with their application to the preparation of various biologically active compounds.
引用
收藏
页码:19 / 24
页数:6
相关论文
共 26 条
[1]  
Bosnich B, 1998, ALDRICHIM ACTA, V31, P76
[2]   USE OF ORGANOMETALLIC COMPLEXES OF RUTHENIUM IN THE LEWIS ACID-CATALYZED HETERO DIELS-ALDER REACTION [J].
FALLER, JW ;
SMART, CJ .
TETRAHEDRON LETTERS, 1989, 30 (10) :1189-1192
[3]   SYNTHESIS OF NOVEL RHENIUM(I) ENOLATE COMPLEXES AS ACTIVE KEY INTERMEDIATES IN THE CATALYTIC ALDOL-TYPE REACTION [J].
HIRANO, M ;
ITO, Y ;
HIRAI, M ;
FUKUOKA, A ;
KOMIYA, S .
CHEMISTRY LETTERS, 1993, (12) :2057-2060
[4]  
Kündig EP, 1999, ANGEW CHEM INT EDIT, V38, P1220
[5]  
Murahashi S. I., IN PRESS
[6]   New way for efficient catalysis by using low valent ruthenium complexes as redox Lewis acid and base catalysts [J].
Murahashi, SI ;
Naota, T .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1996, 69 (07) :1805-1824
[7]   PALLADIUM CATALYZED AMINE EXCHANGE-REACTION OF TERTIARY-AMINES - INSERTION OF PALLADIUM(O) INTO CARBON-HYDROGEN BONDS [J].
MURAHASHI, SI ;
HIRANO, T ;
YANO, T .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (01) :348-350
[8]   RUTHENIUM-CATALYZED HYDRATION OF NITRILES AND TRANSFORMATION OF DELTA-KETO NITRILES TO ENE-LACTAMS [J].
MURAHASHI, SI ;
SASAO, S ;
SAITO, E ;
NAOTA, T .
JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (09) :2521-2523
[9]   RUTHENIUM-CATALYZED HYDRATION OF NITRILES AND TRANSFORMATION OF DELTA-KETONITRILES TO ENE-LACTAMS - TOTAL SYNTHESIS OF (-)-PUMILIOTOXIN-C [J].
MURAHASHI, SI ;
SASAO, S ;
SAITO, E ;
NAOTA, T .
TETRAHEDRON, 1993, 49 (39) :8805-8826
[10]   PALLADIUM CATALYZED-HYDROLYSIS OF TERTIARY-AMINES WITH WATER [J].
MURAHASHI, SI ;
WATANABE, T .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (24) :7429-7430