How deposition parameters control growth dynamics of nc-Si deposited by hot-wire chemical vapor deposition

被引:9
作者
Moutinho, HR [1 ]
To, B [1 ]
Jiang, CS [1 ]
Xu, Y [1 ]
Nelson, BP [1 ]
Teplin, CW [1 ]
Jones, KM [1 ]
Perkins, J [1 ]
Al-Jassim, MM [1 ]
机构
[1] Natl Renewable Energy Lab, Golden, CO 80401 USA
来源
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A | 2006年 / 24卷 / 01期
关键词
D O I
10.1116/1.2137331
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
We studied the growth of silicon films deposited by hot-wire chemical vapor deposition under different values of filament current, substrate temperature, and hydrogen dilution ratio. The physical and electrical properties of the films were Studied by Raman spectroscopy, x-ray diffraction, atomic force microscopy, conductive-atomic force microscopy, and transmission electron microscopy. There is all interdependence of the growth parameters, and films grown with different parameters can have similar structures. We discuss why this interdependence occurs and how it influences the properties of the deposited films, as well as the deposition rate. In general, the films have a complex structure, with a mixture of amorphous, (220)-oriented crystalline and nanocrystalline phases present in most cases. The amount of each phase call be controlled by the variation of one or more of the growth parameters at a time. (c) 2006 American Vacuum Society.
引用
收藏
页码:95 / 102
页数:8
相关论文
共 20 条
[1]   Effects of high hydrogen dilution on the optical and electrical properties in B-doped nc-Si:H thin films [J].
Chen, H ;
Gullanar, MH ;
Shen, WZ .
JOURNAL OF CRYSTAL GROWTH, 2004, 260 (1-2) :91-101
[2]   PRODUCTION OF HIGH-QUALITY AMORPHOUS-SILICON FILMS BY EVAPORATIVE SILANE SURFACE DECOMPOSITION [J].
DOYLE, J ;
ROBERTSON, R ;
LIN, GH ;
HE, MZ ;
GALLAGHER, A .
JOURNAL OF APPLIED PHYSICS, 1988, 64 (06) :3215-3223
[3]  
HEINTZE M, 1993, J NON-CRYST SOLIDS, V166, P985, DOI 10.1016/0022-3093(93)91163-W
[4]   Carrier transport in polycrystalline silicon thin film solar cells grown on a highly textured structure [J].
Honda, S ;
Takakura, H ;
Hamakawa, Y ;
Muhida, R ;
Kawamura, T ;
Harano, T ;
Toyama, T ;
Okamoto, H .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS BRIEF COMMUNICATIONS & REVIEW PAPERS, 2004, 43 (9A) :5955-5959
[5]   Electronic and topographic properties of amorphous and microcrystalline silicon thin films [J].
Kleider, JP ;
Longeaud, C ;
Brüggemann, R ;
Houzé, F .
THIN SOLID FILMS, 2001, 383 (1-2) :57-60
[6]  
KLEIN S, 2002, MAT RES SOC S P, V715
[7]   Characterization of silicon gate oxides by conducting atomic force microscopy [J].
Kremmer, S ;
Teichert, C ;
Pischler, E ;
Gold, H ;
Kuchar, F ;
Schatzmayr, M .
SURFACE AND INTERFACE ANALYSIS, 2002, 33 (02) :168-172
[8]   Formation of silicon-based thin films prepared by catalytic chemical vapor deposition (Cat-CVD) method [J].
Matsumura, H .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 1998, 37 (6A) :3175-3187
[9]  
Meier J, 2004, THIN SOLID FILMS, V451, P518, DOI 10.1016/j.tsf.2003.11.014
[10]   Effects of dilution ratio and seed layer on the crystallinity of microcrystalline silicon thin films deposited by hot-wire chemical vapor deposition [J].
Moutinho, HR ;
Jiang, CS ;
Perkins, J ;
Xu, Y ;
Nelson, BP ;
Jones, KM ;
Romero, MJ ;
Al-Jassim, MM .
THIN SOLID FILMS, 2003, 430 (1-2) :135-140