Asymmetric hydration of allyl alcohol catalyzed by polysulfostyrene-gelatin-Co complex

被引：10

作者：

Zhang, X ^{[1
]}

Li, YJ ^{[1
]}

Huang, MY ^{[1
]}

Jiang, YY ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Chem, Grp 4060, Beijing 100080, Peoples R China

来源：

POLYMERS FOR ADVANCED TECHNOLOGIES | 2002年 / 13卷 / 3-4期

关键词：

asymmetric hydration; allyl alcohol; poly-sulfostyrene-gelatin-Co complex catalyst; (S)-(-)-1,2-propanediol;

D O I：

10.1002/pat.190

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A new dural polymer-metal complex, polysulfostyrene-gelatin -cobalt complex (PSS-GE-Co) has been prepared and found to be able to catalyze the asymmetric hydration Of allyl alcohol to give (S)-(-)-1,2-propanediol in 98% yield with 98.9% optical yield. The catalyst is very stable and can be reused without any remarkable effect in catalytic activity and optical selectivity. Copyright (C) 2002 John Wiley Sons, Ltd.

引用

页码：305 / 309

页数：5

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