Formation of polymeric films on cellulosic surfaces by admicellar polymerization

被引:46
作者
Boufi, S
Gandini, A
机构
[1] Fac Sci Sfax, Lab Physicochim Solide, Sfax 3038, Tunisia
[2] INPG, Ecole Francaise Papeterie & Ind Graph, F-38402 St Martin Dheres, France
关键词
admicelles; cellulose fibers; monomer adsorption; surface polymerisation;
D O I
10.1023/A:1015137116216
中图分类号
TB3 [工程材料学]; TS [轻工业、手工业、生活服务业];
学科分类号
0805 ; 080502 ; 0822 ;
摘要
Cellulose fibers suspended in an aqueous medium were placed in contact with increasing amounts of either a cationic or an anionic surfactant. Only the former was adsorbed, forming admicellar morphologies. The addition of alkenyl monomers to these systems and their subsequent polymerization resulted in the formation of polymer both in the aqueous medium and around the fibers. The latter 'coating', which was rather irregular in coverage, produced a strong increase in the hydrophobic character of the cellulosic surface.
引用
收藏
页码:303 / 312
页数:10
相关论文
共 21 条
[1]   An apparatus for the characterization of the static and dynamic wettability of complex interfaces [J].
Aurenty, P ;
Lanet, V ;
Tessadro, A ;
Gandini, A .
REVIEW OF SCIENTIFIC INSTRUMENTS, 1997, 68 (04) :1801-1808
[2]   ADMICELLAR CHROMATOGRAPHY - SEPARATION AND CONCENTRATION OF ISOMERS USING TWO-DIMENSIONAL SOLVENTS [J].
BARTON, JW ;
FITZGERALD, TP ;
LEE, C ;
OREAR, EA ;
HARWELL, JH .
SEPARATION SCIENCE AND TECHNOLOGY, 1988, 23 (6-7) :637-660
[3]  
BELGACEM MN, 1998, INTERFACIAL PHENOMEN
[4]  
BRIANT J, 1989, PHENOMENES INTERFACE
[5]   ADSOLUBILIZATION BEHAVIOR OF DYES CAUSED BY MIXED SURFACTANT BILAYERS FORMED ON ALUMINA [J].
ESUMI, K ;
SAKAMOTO, Y ;
NAGAHAMA, T ;
MEGURO, K .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1989, 62 (08) :2502-2506
[6]   ADSOLUBILIZATION OF ALCOHOLS IN SURFACTANT BILAYERS FORMED ON ALUMINA [J].
ESUMI, K ;
SHIBAYAMA, M ;
MEGURO, K .
LANGMUIR, 1990, 6 (04) :826-829
[7]  
GAUDIN AM, 1955, T AM I MIN MET ENG, V202, P958
[8]   PSEUDOPHASE SEPARATION MODEL FOR SURFACTANT ADSORPTION - ISOMERICALLY PURE SURFACTANTS [J].
HARWELL, JH ;
HOSKINS, JC ;
SCHECHTER, RS ;
WADE, WH .
LANGMUIR, 1985, 1 (02) :251-262
[9]  
JENGYUE W, 1987, LANGMUIR, V3, P531
[10]   Absolubilization of styrene and isoprene in cetyltrimethylammonium bromide admicelle on precipitated silica [J].
Kitiyanan, B ;
OHaver, JH ;
Harwell, JH ;
Osuwan, S .
LANGMUIR, 1996, 12 (09) :2162-2168