Fluorinated electrolytes for 5 V lithium-ion battery chemistry

被引：512

作者：

Zhang, Zhengcheng ^{[1
]}

Hu, Libo ^{[1
]}

Wu, Huiming ^{[1
]}

Weng, Wei ^{[1
]}

Koh, Meiten ^{[3
]}

Redfern, Paul C. ^{[2
]}

Curtiss, Larry A. ^{[2
]}

Amine, Khalil ^{[1
,4
]}

机构：

[1] Argonne Natl Lab, Chem Sci & Engn Div, Argonne, IL 60439 USA

[2] Argonne Natl Lab, Div Mat Sci, Argonne, IL 60439 USA

[3] Daikin Ind Ltd, Settsu, Osaka, Japan

[4] King Abdulaziz Univ, Jeddah 21413, Saudi Arabia

来源：

ENERGY & ENVIRONMENTAL SCIENCE | 2013年 / 6卷 / 06期

关键词：

SULFONE-BASED ELECTROLYTES; FLUOROETHYLENE CARBONATE; CATHODE; PERFORMANCE; STABILITY; DINITRILE; LIQUIDS;

D O I：

10.1039/c3ee24414h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An electrolyte based on fluorinated carbonate solvents was evaluated with high voltage cathode materials at elevated temperature. The theoretically high anodic stability of these new electrolytes was supported by electrochemical evaluation results using LiNi0.5Mn1.5O4/Li and LiNi0.5Mn1.5O4/Li4Ti5O12 electrochemical couples. Fluorinated carbonate appears to be a suitable electrolyte candidate for transition metal oxide cathodes at high voltage (5 V vs. Li+/Li).

引用

页码：1806 / 1810

页数：5

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