New developments on the photochlorination of C-60 and C-70 fullerene and preparation of fullerene derivatives: Polyfluorofullerenes and polyfullerols.

被引：26

作者：

Cataldo, F

机构：

[1] PROGEGA s.n.c., 00128 Rome

来源：

FULLERENE SCIENCE AND TECHNOLOGY | 1996年 / 4卷 / 05期

关键词：

D O I：

10.1080/10641229608001161

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Improved methods for photochlorination of C-60 and C-70 are described. The photoproducts fit respectively the average formulas C60Cl40 and C70Cl47. It is also shown that these photoproducts can be easily fluorinated by means of KF to give fluorofullerenes. Polyhydroxyfullerene (fullerol) can be easily produced by the action of a methanolic solution of alkali over C60Cl40.

引用

页码：1041 / 1059

页数：19

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