Three p-carboxyphenyl groups possessing zinc porphyrins: efficient, stable, and cost-effective sensitizers for dye-sensitized solar cells

被引:30
作者
Ambre, Ram B. [1 ]
Chang, Gao-Fong [1 ]
Hung, Chen-Hsiung [1 ]
机构
[1] Acad Sinica, Inst Chem, Taipei 115, Taiwan
关键词
D O I
10.1039/c3cc47985d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Zinc porphyrins possessing three p-carboxyphenyl anchoring groups with various substituents were prepared by a facile three-step route in good yields. Zn1NH3A with electron donating and anti-aggregation meso substituents has achieved the highest efficiency of 6.10%. These porphyrins with three p-carboxyphenyl groups are more stable toward photo-bleaching than their single anchoring group analogs.
引用
收藏
页码:725 / 727
页数:3
相关论文
共 21 条
[1]   Effects of Porphyrinic meso-Substituents on the Photovoltaic Performance of Dye-Sensitized Solar Cells: Number and Position of p-Carboxyphenyl and Thienyl Groups on Zinc Porphyrins [J].
Ambre, Ram ;
Chen, Kwan-Bo ;
Yao, Ching-Fa ;
Luo, Liyang ;
Diau, Eric Wei-Guang ;
Hung, Chen-Hsiung .
JOURNAL OF PHYSICAL CHEMISTRY C, 2012, 116 (22) :11907-11916
[2]   New Dual Donor-Acceptor (2D--2A) Porphyrin Sensitizers for Stable and Cost-Effective Dye-Sensitized Solar Cells [J].
Ambre, Ram B. ;
Chang, Gao-Fong ;
Zanwar, Manoj R. ;
Yao, Ching-Fa ;
Diau, Eric Wei-Guang ;
Hung, Chen-Hsiung .
CHEMISTRY-AN ASIAN JOURNAL, 2013, 8 (09) :2144-2153
[3]  
Balaban TS, 2000, EUR J ORG CHEM, V2000, P4047
[4]   Highly Efficient Mesoscopic Dye-Sensitized Solar Cells Based on Donor-Acceptor-Substituted Porphyrins [J].
Bessho, Takeru ;
Zakeeruddin, Shaik M. ;
Yeh, Chen-Yu ;
Diau, Eric Wei-Guang ;
Graetzel, Michael .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (37) :6646-6649
[5]   Porphyrins as light harvesters in the dye-sensitised TiO2 solar cell [J].
Campbell, WM ;
Burrell, AK ;
Officer, DL ;
Jolley, KW .
COORDINATION CHEMISTRY REVIEWS, 2004, 248 (13-14) :1363-1379
[6]   Dye-Sensitized Solar Cells [J].
Hagfeldt, Anders ;
Boschloo, Gerrit ;
Sun, Licheng ;
Kloo, Lars ;
Pettersson, Henrik .
CHEMICAL REVIEWS, 2010, 110 (11) :6595-6663
[7]  
Hardin BE, 2012, NAT PHOTONICS, V6, P162, DOI [10.1038/NPHOTON.2012.22, 10.1038/nphoton.2012.22]
[8]   Synthesis and characterization of porphyrin sensitizers with various electron-donating substituents for highly efficient dye-sensitized solar cells [J].
Hsieh, Chou-Pou ;
Lu, Hsueh-Pei ;
Chiu, Chien-Lan ;
Lee, Cheng-Wei ;
Chuang, Shu-Han ;
Mai, Chi-Lun ;
Yen, Wei-Nan ;
Hsu, Shun-Ju ;
Diau, Eric Wei-Guang ;
Yeh, Chen-Yu .
JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (06) :1127-1134
[9]   Large π-Aromatic Molecules as Potential Sensitizers for Highly Efficient Dye-Sensitized Solar Cells [J].
Imahori, Hiroshi ;
Umeyama, Tomokazu ;
Ito, Seigo .
ACCOUNTS OF CHEMICAL RESEARCH, 2009, 42 (11) :1809-1818
[10]   Novel D-π-A structured Zn(II)-porphyrin dyes containing a bis(3,3-dimethylfluorenyl)amine moiety for dye-sensitised solar cells [J].
Kang, Min Soo ;
Kang, Sung Ho ;
Kim, Sang Gyun ;
Choi, In Taek ;
Ryu, Jung Ho ;
Ju, Myung Jong ;
Cho, Daeheum ;
Lee, Jin Yong ;
Kim, Hwan Kyu .
CHEMICAL COMMUNICATIONS, 2012, 48 (75) :9349-9351