Water complexation as a means of stabilizing the metastable HO3 radical

被引：33

作者：

Aloisio, S

Francisco, JS ^{[1
]}

机构：

[1] Purdue Univ, Dept Chem, W Lafayette, IN 47907 USA

[2] Purdue Univ, Dept Earth & Atmospher Sci, W Lafayette, IN 47907 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1999年 / 121卷 / 37期

关键词：

D O I：

10.1021/ja991001y

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The metastable intermediate HO3 is found to be stabilized by formation of a complex with water. We have calculated the geometry and energy of the HO3-H2O complex, which is 6.5 kcal mol(-1) lower in energy than isolated HO3 and H2O.

引用

页码：8592 / 8596

页数：5

共 31 条

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