Oxygen exchange kinetics on solid oxide fuel cell cathode materials-general trends and their mechanistic interpretation

被引：98

作者：

Wang, Lei ^{[1
]}

Merkle, Rotraut ^{[1
]}

Mastrikov, Yuri A. ^{[1
,2
]}

Kotomin, Eugene A. ^{[1
]}

Maier, Joachim ^{[1
]}

机构：

[1] Max Planck Inst Solid State Res, D-70569 Stuttgart, Germany

[2] Univ Maryland, College Pk, MD 20742 USA

来源：

JOURNAL OF MATERIALS RESEARCH | 2012年 / 27卷 / 15期

关键词：

EPITAXIAL THIN-FILMS; SURFACE EXCHANGE; ELECTRICAL-CONDUCTIVITY; LA1-XSRXMN1-YCOYO3+/-DELTA PEROVSKITES; TRANSPORT-PROPERTIES; ELECTRONIC-STRUCTURE; DIFFUSION PROPERTIES; SEEBECK COEFFICIENT; REDUCTION KINETICS; DEFECT;

D O I：

10.1557/jmr.2012.186

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The compilation of measured effective rate constants for oxygen surface exchange on mixed conducting perovskites, which covers a great variety of compositions ranging from (La,Sr)MnO3 - delta to (La,Sr)(Co,Fe)O3 - delta and (Ba,Sr)(Co,Fe)O3 - delta, demonstrates the importance of ionic conductivity-i.e., high oxygen vacancy concentration as well as vacancy mobility-as a key factor for the surface oxygen exchange rate. This interpretation is corroborated by ab initio calculations, which indicate that the approach of an oxygen vacancy to oxygen intermediates adsorbed on the surface is the rate determining step for a number of perovskites.

引用

页码：2000 / 2008

页数：9

共 62 条

[1] Mechanisms and rate laws for oxygen exchange on mixed-conducting oxide surfaces [J].

Adler, S. B. ;

Chen, X. Y. ;

Wilson, J. R. .

JOURNAL OF CATALYSIS, 2007, 245 (01) :91-109

[2] Quantitative comparison of mixed conducting SOFC cathode materials by means of thin film model electrodes [J].

Baumann, F. S. ;

Fleig, J. ;

Cristiani, G. ;

Stuhlhofer, B. ;

Habermeier, H.-U. ;

Maier, J. .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2007, 154 (09) :B931-B941

[3] Ba0.5Sr0.5Co0.8Fe0.2O3-δ thin film microelectrodes investigated by impedance spectroscopy [J].

Baumann, F. S. ;

Fleig, J. ;

Habermeier, H. -U. ;

Maier, J. .

SOLID STATE IONICS, 2006, 177 (35-36) :3187-3191

[4] Oxygen tracer diffusion and surface exchange kinetics in La0.6Sr0.4CoO3-δ [J].

Berenov, A. V. ;

Atkinson, A. ;

Kilner, J. A. ;

Bucher, E. ;

Sitte, W. .

SOLID STATE IONICS, 2010, 181 (17-18) :819-826

[5] Microstructural and high-temperature electrical characterization of La1-xSrxFeO3-δ [J].

Bongio, EV ;

Black, H ;

Raszewski, FC ;

Edwards, D ;

McConville, CJ ;

Amarakoon, VRW .

JOURNAL OF ELECTROCERAMICS, 2005, 14 (03) :193-198

[6] A novel pulse isotopic exchange technique for rapid determination of the oxygen surface exchange rate of oxide ion conductors [J].

Bouwmeester, Henny J. M. ;

Song, Chunlin ;

Zhu, Jianjun ;

Yi, Jianxin ;

Annaland, Martin van Sint ;

Boukamp, Bernard A. .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2009, 11 (42) :9640-9643

[7] Defect equilibria and partial molar properties of (La,Sr)(Co,Fe)O3-δ [J].

Bucher, E. ;

Sitte, W. ;

Caraman, G. B. ;

Cherepanov, V. A. ;

Aksenova, T. V. ;

Ananyev, M. V. .

SOLID STATE IONICS, 2006, 177 (35-36) :3109-3115

[8] Anisotropic oxygen diffusion properties in epitaxial thin films of La2NiO4+δ [J].

Burriel, Monica ;

Garcia, Gemma ;

Santiso, Jose ;

Kilner, John A. ;

Richard, J. Chater C. ;

Skinner, Stephen J. .

JOURNAL OF MATERIALS CHEMISTRY, 2008, 18 (04) :416-422

[9] BSCF epitaxial thin films: Electrical transport and oxygen surface exchange [J].

Burriel, Monica ;

Niedrig, Christian ;

Menesklou, Wolfgang ;

Wagner, Stefan F. ;

Santiso, Jose ;

Ivers-Tiffee, Ellen .

SOLID STATE IONICS, 2010, 181 (13-14) :602-608

[10] Surface exchange and bulk diffusion properties of Ba0.5Sr0.5Co0.8Fe0.2O3-δ mixed conductor [J].

Chen, Dengjie ;

Shao, Zongping .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2011, 36 (11) :6948-6956

← 1 2 3 4 5 6 7 →