A catalytic approach to (R)-(+)-muscopyridine with integrated "self-clearance"

被引:205
作者
Fürstner, A [1 ]
Leitner, A [1 ]
机构
[1] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany
关键词
cross-coupling; iron; macrocycles; metathesis; ruthenium;
D O I
10.1002/anie.200390103
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The integration of various metal-catalyzed reactions into a one-pot processes opens an unprecedentedly short and efficient route to the odoriferous alkaloid (R)-(+)-muscopyridine. Importantly, it is shown how metathesis can be used for a most convenient self-clearance" of a product mixture (see scheme; OTf= CF3SO3)."
引用
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页码:308 / +
页数:5
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