Preparation of trifluoromethyl sulfides or selenides from trifluoromethyl trimethylsilane and thiocyanates or selenocyanates

被引：172

作者：

Billard, T ^{[1
]}

Large, S ^{[1
]}

Langlois, BR ^{[1
]}

机构：

[1] UNIV LYON 1,CNRS,LAB CHIM ORGAN 3,F-69622 VILLEURBANNE,FRANCE

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 01期

关键词：

D O I：

10.1016/S0040-4039(96)02216-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Trifluoromethyl sulfides (or selenides) are easily obtained in one pot at 0 degrees C from thiocyanates (or selenocyanates), commercial trifluoromethyl trimethylsilane and catalytic amounts of tetrabutylammonium fluoride (TBAF). Copyright (C) 1996 Elsevier Science Ltd

引用

页码：65 / 68

页数：4

共 15 条

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[8] REACTIONS OF TRIFLUOROMETHYL BROMIDE AND RELATED HALIDES .10. PERFLUOROALKYLATION OF AROMATIC-COMPOUNDS INDUCED BY SULFUR-DIOXIDE RADICAL-ANION PRECURSORS
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[9] UMEMOTO T, 1990, TETRAHEDRON LETT, V31, P3579
[10] UMEMOTO T, 1995, Patent No. 95126245

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