Selective Gas and Vapor Sorption and Magnetic Sensing by an Isoreticular Mixed-Metal-Organic Framework

被引：107

作者：

Ferrando-Soria, Jesus ^{[1
]}

Serra-Crespo, Pablo ^{[2
]}

de Lange, Martijn ^{[2
]}

Gascon, Jorge ^{[2
]}

Kapteijn, Freek ^{[2
]}

Julve, M. ^{[1
]}

Cano, J. ^{[1
]}

Lloret, Francesc ^{[1
]}

Pasan, Jorge ^{[3
]}

Ruiz-Perez, Catalina ^{[3
]}

Journaux, Yves ^{[4
]}

Pardo, Emilio ^{[1
]}

机构：

[1] Univ Valencia, Inst Ciencia Mol, Dept Quim Inorgan, ES-46980 Paterna, Valencia, Spain

[2] Delft Univ Technol, Catalysis Engn Chem Engn Dept, NL-2628 BL Delft, Netherlands

[3] Univ Laguna, Dept Fis Fundamental II, Lab Rayos X & Mat Mol, E-38201 Tenerife, Spain

[4] Univ Pierre & Marie Curie Paris 6, Inst Parisien Chim Mol, UMR CNRS 7201, F-75252 Paris 05, France

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2012年 / 134卷 / 37期

基金：

中国国家自然科学基金;

关键词：

RATIONAL DESIGN;

D O I：

10.1021/ja3045822

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel isoreticular oxamato-based manganese(II-copper(II) open metal-organic framework H subset of 2O@iso1 featuring a pillared square/octagonal layer structure with alternating open and closed octagonal pores has been rationally prepared. The open-framework topology is responsible for a large selectivity in the separation of small gas (CO subset of 2 over CH subset of 4) and vapor molecules (CH subset of 3OH over CH subset of 3CN and CH subset of 3CH subset of 2OH). H subset of 2O@iso1 displays a long-range three-dimensional ferromagnetic ordering with a drastic variation of the critical temperature as a function of the guest molecule [T subset of C < 2.0 K (CO subset of 2@iso1 and CH subset of 4@iso1) and T subset of C = 6.5 (CH subset of 3OH@iso1) and 21.0 K (H subset of 2O@iso1)].

引用

页码：15301 / 15304

页数：4

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