Microporous magnets

被引：500

作者：

Dechambenoit, Pierre ^{[1
]}

Long, Jeffrey R. ^{[1
]}

机构：

[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

来源：

CHEMICAL SOCIETY REVIEWS | 2011年 / 40卷 / 06期

关键词：

PRUSSIAN BLUE ANALOGS; METAL-ORGANIC FRAMEWORK; SINGLE-CRYSTAL TRANSFORMATION; NANOPOROUS NICKEL PHOSPHATES; HYDROGEN STORAGE; DIAMOND FRAMEWORK; SPIN-CROSSOVER; HYDROTHERMAL SYNTHESIS; COORDINATION POLYMER; POWDER-DIFFRACTION;

D O I：

10.1039/c0cs00167h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Combining porosity and magnetic ordering in a single material presents a significant challenge since magnetic exchange generally requires short bridges between the spin carriers, whereas porosity usually relies on the use of long diamagnetic connecting ligands. Despite this apparent incompatibility, notable successes have been achieved of late in generating truly microporous solids with high magnetic ordering temperatures. In this critical review, we give an overview of this emerging class of multifunctional materials, with particular emphasis on synthetic strategies and possible routes to new materials with improved properties (149 references).

引用

页码：3249 / 3265

页数：17

共 155 条

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