Reactions of a Stable Monomeric Gold(I) Hydride Complex

被引：172

作者：

Tsui, Emily Y. ^{[1
]}

Mueller, Peter ^{[1
]}

Sadighi, Joseph P. ^{[1
]}

机构：

[1] MIT, Dept Chem, Cambridge, MA 02139 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 46期

关键词：

carbene ligands; diazo compounds; gold; hydrides; insertion;

D O I：

10.1002/anie.200803842

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Golden opportunity: A terminal mononuclear gold(I) hydride complex has been stabilized by an N-heterocyclic carbene ligand (see picture: Au orange, N blue, C gray). The complex is stable to a wider range of conditions than other transition metal hydride compounds and reacts to form a number of different gold(I) species. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

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页码：8937 / 8940

页数：4

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