Analysis of the native structure of starch granules with X-ray microfocus diffraction

被引:113
作者
Waigh, TA
Hopkinson, I
Donald, AM
Butler, MF
Heidelbach, F
Riekel, C
机构
[1] UNIV CAMBRIDGE,CAVENDISH LAB,CAMBRIDGE CB3 0HE,ENGLAND
[2] DEPT MAT SCI & MET,CAMBRIDGE CB2 3QJ,ENGLAND
[3] EUROPEAN SYNCHROTRON RADIAT FACIL,F-38043 GRENOBLE,FRANCE
关键词
D O I
10.1021/ma970075w
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Results of microfocus X-ray diffraction at the ESRF are presented which provide unique evidence supporting a model for the structure of starch, much of this model having been previously derived only on the basis of circumstantial evidence. Here we present data from similar to 2 mu m regions within granules which have been subjected to no sample preparation and obtain oriented 2-D fiber patterns from the edge of B-type potato starch granules. This data is in good agreement with that previously calculated by Imberty/Perez(1) for a B-type amylose fiber. The peripheral amylopectin helices are oriented in such a way they do not point to a single focus. No discontinuities (''grain boundaries'') within a granule could be found at the 10 mu m level of resolution.
引用
收藏
页码:3813 / 3820
页数:8
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