Reduced graphene oxide: firm support for catalytically active palladium nanoparticles and game changer in selective hydrogenation reactions

被引：26

作者：

Cano, Manuela ^{[1
]}

Benito, Ana M. ^{[1
]}

Urriolabeitia, Esteban P. ^{[2
]}

Arenal, Raul ^{[3
,4
]}

Maser, Wolfgang K. ^{[1
]}

机构：

[1] Inst Carboquim ICB CSIC, E-50018 Zaragoza, Spain

[2] Univ Zaragoza, CSIC, ISQCH, E-50009 Zaragoza, Spain

[3] Univ Zaragoza, LMA INA, E-50018 Zaragoza, Spain

[4] Fdn ARAID, E-50018 Zaragoza, Spain

来源：

NANOSCALE | 2013年 / 5卷 / 21期

关键词：

CARBON NANOTUBES; CATALYSTS; DEHYDROGENATION; ISOMERIZATION; ACETOPHENONE; DERIVATIVES; GRAPHITE;

D O I：

10.1039/c3nr02822d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Simultaneous decomposition and reduction of a Pd2+ complex in the presence of graphene oxide (GO) lead to the formation of Pd-0-nanoparticles (Pd-NPs) with average sizes of 4 nm firmly anchored on reduced graphene oxide (RGO) sheets. The Pd-NP/RGO hybrids exhibited remarkable catalytic activity and selectivity in mild hydrogenation reactions where the acidic properties of RGO play an active role and may act as an important game-changer.

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收藏

页码：10189 / 10193

页数：5

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