Olefin isomerization by a ruthenium carbenoid complex. Cleavage of allyl and homoallyl groups

被引：115

作者：

Cadot, C ^{[1
]}

Dalko, PI ^{[1
]}

Cossy, J ^{[1
]}

机构：

[1] ESPCI, CNRS, Chim Organ Lab, F-750231 Paris 05, France

来源：

TETRAHEDRON LETTERS | 2002年 / 43卷 / 10期

关键词：

alkenes; isomerization; protecting groups;

D O I：

10.1016/S0040-4039(02)00141-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Ruthenium-carbenoid catalysts such as Grubbs' complex I mediate efficiently the isomerization of beta,gamma-unsaturated ethers and amines to the corresponding vinyl ethers and enamines. This reaction can be useful in the deprotection of allyl and homoallyl ethers as well as amines. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：1839 / 1841

页数：3

共 57 条

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