Novel dialkyl aluminum bis(iminophosphorano) methanide and methanediide complexes

被引：91

作者：

Aparna, K ^{[1
]}

McDonald, R ^{[1
]}

Ferguson, M ^{[1
]}

Cavell, RG ^{[1
]}

机构：

[1] Univ Alberta, Dept Chem, Edmonton, AB T6G 2G2, Canada

来源：

ORGANOMETALLICS | 1999年 / 18卷 / 21期

关键词：

D O I：

10.1021/om990486w

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of bis{trimethylsilyliminodi(phenyl)-phosphorano}methane, H2C(Ph2P=NSiMe3)(2) (1) with 1 equiv of trimethylaluminum in toluene gave a four-coordinated alkyl aluminum complex of the formula [AlMe2{HC(Ph2P=NSiMe3)(2)-kappa(2)N,N'}] (2) via the elimination of methane. The crystal structure confirms the monomeric nature of the complex: and the bidentate coordination of the bisiminophosphoranomethanide ligand to aluminum. Reaction of 1 with 2 eguiv of trimethylaluminum yielded the novel bimetallic complex [(AlMe2)(2){mu(2)-C(Ph2P=NSiMe3)(2)-kappa(4)C,C',N,N'}] (3), in which the methylene backbone carbon has been doubly deprotonated.

引用

页码：4241 / 4243

页数：3

共 38 条

[1] Aluminum alkyl complexes containing guanidinate ligands [J].