Hydrogen bonded supramolecular network in organic salts: crystal structures of acid-base salts of dicarboxylic acids and amines

被引:105
作者
Ballabh, A [1 ]
Trivedi, DR [1 ]
Dastidar, P [1 ]
Suresh, E [1 ]
机构
[1] Cent Salt & Marine Chem Res Inst, Silicates & Catalysis Div, Xray Lab, Bhavnagar 364002, Gujarat, India
来源
CRYSTENGCOMM | 2002年 / 4卷 / 24期
关键词
D O I
10.1039/b202113g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Four new organic salts, namely bis(2-aminopyridinium) fumarate-fumaric acid (1 : 1) 1, benzylammonium hydrogen fumarate 2, 2-aminopyridinium hydrogen cyclobutane-1,1-dicarboxylate 3 and benzylammonium hydrogen cyclobutane-1,1-dicarboxylate 4 have been synthesized and characterized by FT-IR, H-1 NMR and single crystal X-ray crystallography in order to analyse their supramolecular structures. While 1, 2 and 4 form two-dimensional layer structures, 3 displays a one-dimensional network. The role of stronger O-H...O and N-H...O interactions and weak C-H..O interactions on the supramolecular arrangement have been discussed based on the single crystal X-ray structures.
引用
收藏
页码:135 / 142
页数:8
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