A Palladium-Catalyzed Dehydrogenative Diamination of Terminal Olefins

被引：98

作者：

Wang, Bin ^{[1
]}

Du, Haifeng ^{[1
]}

Shi, Yian ^{[1
]}

机构：

[1] Colorado State Univ, Dept Chem, Ft Collins, CO 80523 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 43期

基金：

美国国家卫生研究院;

关键词：

amination; dehydrogenation; palladium; terminal olefins;

D O I：

10.1002/anie.200803184

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) A dynamic diamination: The title transformation has been developed with diaziridine 1 as the nitrogen source (see scheme; dba=trans,trans-dibenzylidene-acetone). The reaction proceeds through an allylic amination and subsequent cyclization, and a variety of terminal olefins can be effectively diaminated with high regioselectivity. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：8224 / 8227

页数：4

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