A Pd(0)-catalyzed diamination of terminal olefins at allylic and homoallylic carbons via formal C-H activation under solvent-free conditions

被引：142

作者：

Du, Haifeng ^{[1
]}

Yuan, Weicheng ^{[1
]}

Zhao, Baoguo ^{[1
]}

Shi, Yian ^{[1
]}

机构：

[1] Colorado State Univ, Dept Chem, Ft Collins, CO 80523 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2007年 / 129卷 / 24期

关键词：

D O I：

10.1021/ja072080d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This paper describes a novel diamination process of terminal olefins at allylic and homoallylic carbons via formal C-H activation using di-tert-butyldiaziridinone as nitrogen source and Pd(PPh3)(4) as catalyst. A wide variety of terminal olefins can be effectively diaminated in good yields with high stereoselectivity.

引用

页码：7496 / +

页数：3

共 30 条

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