A facile Pd(0)-catalyzed regio- and stereoselective diamination of conjugated dienes and trienes

被引：218

作者：

Du, Haifeng ^{[1
]}

Zhao, Baoguo ^{[1
]}

Shi, Yian ^{[1
]}

机构：

[1] Colorado State Univ, Dept Chem, Ft Collins, CO 80523 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2007年 / 129卷 / 04期

关键词：

D O I：

10.1021/ja0680562

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This paper describes a novel diamination process using di-t-butyldiaziridinone as the nitrogen source and Pd(PPh3)(4) as catalyst. A wide variety of conjugated dienes and trienes can be effectively diaminated in good yields with high regio- and stereoselectivities in short reaction time.

引用

页码：762 / 763

页数：2

共 32 条

[1] ARANDA VG, 1974, SYNTHESIS-STUTTGART, P504
[2] BACKVALL JE, 1978, TETRAHEDRON LETT, V163, pT1
[3] Pd(II)-catalyzed intermolecular 1,2-diamination of conjugated dienes
Bar, GLJ
Lloyd-Jones, GC
Booker-Milburn, KI
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (20) : 7308 - 7309
[4] BARLUENGA J, 1979, SYNTHESIS-STUTTGART, P962
[5] A NEW METHOD FOR 1,2-DIAMINATION OF ALKENES USING CYCLOPENTADIENYLNITROSYLCOBALT DIMER-NO-LIALH4
BECKER, PN
WHITE, MA
BERGMAN, RG
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (17) : 5676 - 5677
[6] Ritter-type reactions of N-chlorosaccharin:: A method for the electrophilic diamination of alkenes
Booker-Milburn, KI
Guly, DJ
Cox, B
Procopiou, PA
[J]. ORGANIC LETTERS, 2003, 5 (18) : 3313 - 3315
[7] Aerobic oxidative amination of unactivated alkenes catalyzed by palladium
Brice, JL
Harang, JE
Timokhin, VI
Anastasi, NR
Stahl, SS
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (09) : 2868 - 2869
[8] SYNTHESIS OF DIOXOBIS(TERT-ALKYLIMIDO)OSMIUM(VIII) AND OXOTRIS(TERT-ALKYLIMIDO)OSMIUM(VIII) COMPLEXES - STEREOSPECIFIC VICINAL DIAMINATION OF OLEFINS
CHONG, AO
OSHIMA, K
SHARPLESS, KB
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (10) : 3420 - 3426
[9] CONVERSION OF ALKENES TO 1,2-DIAZIDES AND 1,2-DIAMINES
FRISTAD, WE
BRANDVOLD, TA
PETERSON, JR
THOMPSON, SR
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1985, 50 (19) : 3647 - 3649
[10] DIAZIRIDINONES (2,3-DIAZACYCLOPROPANONES) .2. SYNTHESIS, PROPERTIES, AND REACTIONS
GREENE, FD
STOWELL, JC
BERGMARK, WR
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1969, 34 (08) : 2254 - &

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