A facile Pd(0)-catalyzed regio- and stereoselective diamination of conjugated dienes and trienes

被引：218

作者：

Du, Haifeng ^{[1
]}

Zhao, Baoguo ^{[1
]}

Shi, Yian ^{[1
]}

机构：

[1] Colorado State Univ, Dept Chem, Ft Collins, CO 80523 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2007年 / 129卷 / 04期

关键词：

D O I：

10.1021/ja0680562

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This paper describes a novel diamination process using di-t-butyldiaziridinone as the nitrogen source and Pd(PPh3)(4) as catalyst. A wide variety of conjugated dienes and trienes can be effectively diaminated in good yields with high regio- and stereoselectivities in short reaction time.

引用

页码：762 / 763

页数：2

共 32 条

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