Growth of noble metal nanoparticles on single-layer TiS2 and TaS2 nanosheets for hydrogen evolution reaction

被引:322
作者
Zeng, Zhiyuan [1 ]
Tan, Chaoliang [1 ]
Huang, Xiao [1 ]
Bao, Shuyu [1 ]
Zhang, Hua [1 ]
机构
[1] Nanyang Technol Univ, Sch Mat Sci & Engn, Singapore 639798, Singapore
基金
新加坡国家研究基金会;
关键词
MOS2 ATOMIC LAYERS; LARGE-AREA; DICHALCOGENIDE NANOSHEETS; THIN-LAYERS; GRAPHENE; EXFOLIATION; FABRICATION; NANOSTRUCTURES; DEPOSITION; CATALYST;
D O I
10.1039/c3ee42620c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The preparation of single-layer TiS2 and TaS2 nanosheets is realized by optimizing the electrochemical lithium interaction and exfoliation method. As a proof of concept, Pt and Au nanoparticles are grown on the aforementioned ultra-thin nanosheets to form functional composites. Notably, the Pt-TiS2 hybrid presents good electrocatalytic activity in the hydrogen evolution reaction.
引用
收藏
页码:797 / 803
页数:7
相关论文
共 40 条
[1]   Atomically thin layers of MoS2 via a two step thermal evaporation-exfoliation method [J].
Balendhran, Sivacarendran ;
Ou, Jian Zhen ;
Bhaskaran, Madhu ;
Sriram, Sharath ;
Ippolito, Samuel ;
Vasic, Zoran ;
Kats, Eugene ;
Bhargava, Suresh ;
Zhuiykov, Serge ;
Kalantar-zadeh, Kourosh .
NANOSCALE, 2012, 4 (02) :461-466
[2]  
Chhowalla M, 2013, NAT CHEM, V5, P263, DOI [10.1038/nchem.1589, 10.1038/NCHEM.1589]
[3]   Two-Dimensional Nanosheets Produced by Liquid Exfoliation of Layered Materials [J].
Coleman, Jonathan N. ;
Lotya, Mustafa ;
O'Neill, Arlene ;
Bergin, Shane D. ;
King, Paul J. ;
Khan, Umar ;
Young, Karen ;
Gaucher, Alexandre ;
De, Sukanta ;
Smith, Ronan J. ;
Shvets, Igor V. ;
Arora, Sunil K. ;
Stanton, George ;
Kim, Hye-Young ;
Lee, Kangho ;
Kim, Gyu Tae ;
Duesberg, Georg S. ;
Hallam, Toby ;
Boland, John J. ;
Wang, Jing Jing ;
Donegan, John F. ;
Grunlan, Jaime C. ;
Moriarty, Gregory ;
Shmeliov, Aleksey ;
Nicholls, Rebecca J. ;
Perkins, James M. ;
Grieveson, Eleanor M. ;
Theuwissen, Koenraad ;
McComb, David W. ;
Nellist, Peter D. ;
Nicolosi, Valeria .
SCIENCE, 2011, 331 (6017) :568-571
[4]   Amorphous oxysulfide thin films MOySz (M = W, Mo, Ti) XPS characterization:: structural and electronic pecularities [J].
Dupin, JC ;
Gonbeau, D ;
Martin-Litas, I ;
Vinatier, P ;
Levasseur, A .
APPLIED SURFACE SCIENCE, 2001, 173 (1-2) :140-150
[5]   CORE AND VALENCE SPECTRA OF TITANIUM DICHALCOGENIDES TIX(2) (WHERE X IS O, S) - EXPERIMENTAL AND THEORETICAL-STUDIES [J].
FABA, MG ;
GONBEAU, D ;
PFISTERGUILLOUZO, G .
JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 1995, 73 (01) :65-80
[6]   A Methanol-Tolerant Pt/CoSe2 Nanobelt Cathode Catalyst for Direct Methanol Fuel Cells [J].
Gao, Min-Rui ;
Gao, Qiang ;
Jiang, Jun ;
Cui, Chun-Hua ;
Yao, Wei-Tang ;
Yu, Shu-Hong .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (21) :4905-4908
[7]   Fabrication of Flexible MoS2 Thin-Film Transistor Arrays for Practical Gas-Sensing Applications [J].
He, Qiyuan ;
Zeng, Zhiyuan ;
Yin, Zongyou ;
Li, Hai ;
Wu, Shixin ;
Huang, Xiao ;
Zhang, Hua .
SMALL, 2012, 8 (19) :2994-2999
[8]   Graphene-based composites [J].
Huang, Xiao ;
Qi, Xiaoying ;
Boey, Freddy ;
Zhang, Hua .
CHEMICAL SOCIETY REVIEWS, 2012, 41 (02) :666-686
[9]   Solution-phase epitaxial growth of noble metal nanostructures on dispersible single-layer molybdenum disulfide nanosheets [J].
Huang, Xiao ;
Zeng, Zhiyuan ;
Bao, Shuyu ;
Wang, Mengfei ;
Qi, Xiaoying ;
Fan, Zhanxi ;
Zhang, Hua .
NATURE COMMUNICATIONS, 2013, 4
[10]   Metal dichalcogenide nanosheets: preparation, properties and applications [J].
Huang, Xiao ;
Zeng, Zhiyuan ;
Zhang, Hua .
CHEMICAL SOCIETY REVIEWS, 2013, 42 (05) :1934-1946