Aerosol Synthesis of Cargo-Filled Graphene Nanosacks

被引:178
作者
Chen, Yantao [2 ]
Guo, Fei [1 ]
Jachak, Ashish [3 ]
Kim, Sang-Pil [1 ]
Datta, Dibakar [1 ]
Liu, Jingyu [2 ]
Kulaots, Indrek [1 ]
Vaslet, Charles [3 ]
Jang, Hee Dong [5 ,6 ]
Huang, Jiaxing [5 ]
Kane, Agnes [3 ,4 ]
Shenoy, Vivek B. [1 ,4 ]
Hurt, Robert H. [1 ,4 ]
机构
[1] Brown Univ, Sch Engn, Providence, RI 02912 USA
[2] Brown Univ, Dept Chem, Providence, RI 02912 USA
[3] Brown Univ, Dept Pathol & Lab Med, Providence, RI 02912 USA
[4] Brown Univ, Inst Mol & Nanoscale Innovat, Providence, RI 02912 USA
[5] Northwestern Univ, Dept Mat Sci & Engn, Evanston, IL 60208 USA
[6] Korea Inst Geosci & Mineral Resources, Rare Met Res Ctr, Taejon 305350, South Korea
基金
美国国家科学基金会;
关键词
Graphene; graphene oxide; encapsulation; folding; core-shell structures; biocompatibility; MOLECULAR-DYNAMICS SIMULATIONS; GRAPHITE OXIDE; SHEETS; NANOPARTICLES; NANOSHEETS; REDUCTION; SILVER; WATER;
D O I
10.1021/nl2045952
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Water micro droplets containing graphene oxide and a second solute are shown to spontaneously segregate into sack-cargo nanostructures upon drying. Analytical modeling and molecular dynamics suggest the sacks form when slow-diffusing graphene oxide preferentially accumulates and adsorbs at the receding air water interface, followed by capillary collapse. Cargo-filled graphene nanosacks can be nanomanufactured by a simple, continuous, scalable process and are promising for many applications where nanoscale materials should be isolated from the environment or biological tissue.
引用
收藏
页码:1996 / 2002
页数:7
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