Aerosol Synthesis of Cargo-Filled Graphene Nanosacks

被引：178

作者：

Chen, Yantao ^{[2
]}

Guo, Fei ^{[1
]}

Jachak, Ashish ^{[3
]}

Kim, Sang-Pil ^{[1
]}

Datta, Dibakar ^{[1
]}

Liu, Jingyu ^{[2
]}

Kulaots, Indrek ^{[1
]}

Vaslet, Charles ^{[3
]}

Jang, Hee Dong ^{[5
,6
]}

Huang, Jiaxing ^{[5
]}

Kane, Agnes ^{[3
,4
]}

Shenoy, Vivek B. ^{[1
,4
]}

Hurt, Robert H. ^{[1
,4
]}

机构：

[1] Brown Univ, Sch Engn, Providence, RI 02912 USA

[2] Brown Univ, Dept Chem, Providence, RI 02912 USA

[3] Brown Univ, Dept Pathol & Lab Med, Providence, RI 02912 USA

[4] Brown Univ, Inst Mol & Nanoscale Innovat, Providence, RI 02912 USA

[5] Northwestern Univ, Dept Mat Sci & Engn, Evanston, IL 60208 USA

[6] Korea Inst Geosci & Mineral Resources, Rare Met Res Ctr, Taejon 305350, South Korea

来源：

NANO LETTERS | 2012年 / 12卷 / 04期

基金：

美国国家科学基金会;

关键词：

Graphene; graphene oxide; encapsulation; folding; core-shell structures; biocompatibility; MOLECULAR-DYNAMICS SIMULATIONS; GRAPHITE OXIDE; SHEETS; NANOPARTICLES; NANOSHEETS; REDUCTION; SILVER; WATER;

D O I：

10.1021/nl2045952

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Water micro droplets containing graphene oxide and a second solute are shown to spontaneously segregate into sack-cargo nanostructures upon drying. Analytical modeling and molecular dynamics suggest the sacks form when slow-diffusing graphene oxide preferentially accumulates and adsorbs at the receding air water interface, followed by capillary collapse. Cargo-filled graphene nanosacks can be nanomanufactured by a simple, continuous, scalable process and are promising for many applications where nanoscale materials should be isolated from the environment or biological tissue.

引用

页码：1996 / 2002

页数：7

共 59 条

[51] Biological Interactions of Graphene-Family Nanomaterials: An Interdisciplinary Review [J].